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供氢剂辅助重油热改质技术研究进展

龚旭 薛鹏 刘贺 陈坤 郭爱军 王宗贤

化工进展2018,Vol.37Issue(4):1374-1380,7.
化工进展2018,Vol.37Issue(4):1374-1380,7.DOI:10.16085/j.issn.1000-6613.2017-1160

供氢剂辅助重油热改质技术研究进展

Progress on the use of hydrogen donors for upgrading of heavy oil

龚旭 1薛鹏 1刘贺 1陈坤 1郭爱军 1王宗贤1

作者信息

  • 1. 中国石油大学(华东)化学工程学院,重质油国家重点实验室,山东 青岛266580
  • 折叠

摘要

Abstract

Due to high viscosity and high density of heavy oil, the viscosity reduction had firstly to be done to ensure heavy oil extraction, gathering, and processing. The hydrogen donated visbreaking process, which the hydrogen donor was added into the conventional visbreaking process to solve the problem of low processing depth,coking,and poor stability,was an efficient thermal viscosity reduction technology. This review first introduced the basic types of heavy oil pipeline transportations. Then the hydrogen donating mechanism,the effect of hydrogen donor,the species of hydrogen donor, determination of donatable hydrogen concentration and application of hydrogen donor were summarized. The selection of hydrogen donors should be determined according to process conditions and the properties of hydrogen donor. The key issue of affecting the coking and inhibiting coking is whether the active hydrogen can be timely closed the asphaltic free radicals.

关键词

供氢剂/重油/黏度/可供氢量/测定方法

Key words

hydrogen donors/heavy oil/viscosity/donatable hydrogen/determination methods

分类

能源科技

引用本文复制引用

龚旭,薛鹏,刘贺,陈坤,郭爱军,王宗贤..供氢剂辅助重油热改质技术研究进展[J].化工进展,2018,37(4):1374-1380,7.

基金项目

中国博士后科学基金(2016M602219)、山东省自然科学基金博士基金(ZR2017BB021)、青岛市博士后应用研究项目(2016224)及重质油国家重点实验室项目(SLKZZ-2017003). (2016M602219)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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