化工进展2018，Vol.37Issue(4)：1433-1441,9.DOI:10.16085/j.issn.1000-6613.2017-1096
负载固相的铑基催化剂应用于烯烃氢甲酰化反应的研究进展
Research progress of immobilized Rh-based catalysts on solid supports for olefin hydroformylation
高李杰 1孟凯 2姜伟丽 1周广林 1周红军 1余长春1
作者信息
- 1. 中国石油大学(北京)新能源研究院,生物燃气高值利用北京市重点实验室,北京102249
- 2. 山东省纤维检验局,山东 济南 250021
- 折叠
摘要
Abstract
Due to its simple separation,easy recycling and excellent catalytic performance, the immobilized Rh-based catalyst on solid supports attracts much attention. However,there are some problems such as poor reactivity,large amount of metal loss and high cost on catalyst preparation. In this paper,the recent progress of these catalysts in recent years is summarized from the perspective of different supported materials. The effects of the surface properties of the supported catalysts, their preparation methods and the phosphine ligands on the catalytic performance are discussed. Finally,the breakthroughs in the new single-atom catalysts are introduced. The results show that the catalytic activity of porous organic polymers is very good,while the stability of hyperbranched polymer functionalized magnetic nano-catalysts is better. Future research should be committed to understanding the chemical structure of porous organic polymers in order to better characterize them,and the effect of the carrier structure on the catalytic performance of single-atom catalysts with the assistance of some advanced characterization techniques such as high-angle annular dark field scanning transmission electron microscopy and density functional theory calculations.关键词
催化剂载体/氢甲酰化反应/多相反应/烯烃/纳米粒子Key words
catalyst support/hydroformylation reaction/multiphase reaction/olefin/nanoparticle分类
化学化工引用本文复制引用
高李杰,孟凯,姜伟丽,周广林,周红军,余长春..负载固相的铑基催化剂应用于烯烃氢甲酰化反应的研究进展[J].化工进展,2018,37(4):1433-1441,9.
