高等学校化学学报Issue(4)：779-784,6.DOI:10.7503/cjcu20170368
以糠醛为原料的成对电合成
Paired Electrosynthesis Using Furfural as Raw Material
摘要
Abstract
In order to choose the best electrode for the electrochemical oxidation of furfural to furfuryl acid, the oxygen evolution and the electrocatalysis for the oxidation of furfural of Ti/Ru-Ti-Sn,Ni,Ti/PbO2,Pt and Ti/BDD were studied.The effects of pH of the solution,current density,concentration of furfural,temperature and electrolysis time on the electrochemical reduction of furfural to furfuryl alcohol and the electrochemical oxidation of furfural to furoic acid were investigated using Ni anode. The results showed that the best current efficiency was 130% at pH=11, cathodic current density 2 mA/cm2, anodic current density 1 mA/cm2, concentration of furfural 0.1 mol/L,temperature 25℃,cathodic electrolysis time 4 h and anodic electrolysis time 6 h.关键词
糠醛/糠酸/糠醇/成对电合成Key words
Furfural/Furfuryl alcohol/Furoic acid/Paired electrosynthesis分类
化学化工引用本文复制引用
刘红红,刘丽超,张文礼,何亚鹏,黄卫民,林海波..以糠醛为原料的成对电合成[J].高等学校化学学报,2018,(4):779-784,6.基金项目
国家自然科学基金(批准号:21273097,21573093)、国家重点研究发展计划项目(批准号:2016YFC1102802)、吉林省重大科技攻关招标项目(批准号:20130204003GX)和广东省引进创新创业团队计划项目(批准号:2013C092)资助.Supported by the National Natural Science Foundation of China(Nos.21273097,21573093),the National Key Research and Development Program,China(No.2016YFC1102802),the Science and Technology Development Project of Jilin Province,China(No.20130204003GX)and the Guangdong Innovative and Entrepreneurial Research Team Program,China(No.2013C092). （批准号:21273097,21573093）
