燃料化学学报2018,Vol.46Issue(4):413-418,6.
催化裂化油浆中烯烃分布研究
Study on olefin distribution of catalytic cracking slurry
摘要
Abstract
The content of conjugated olefins (double bonds) and olefins (double bonds) in four fractions and five fractions of a FCC slurry was determined by the diene number and bromine number analysis method. UV and 1H-NMR were used to characterize and determine the type and content of olefins in the four fractions and five fractions. The results confirm that the olefin (double bond) and conjugated olefin (double bond) exist in FCC slurry,the contents of olefin(double bond) and conjugated olefin(double bond) are as high as 21% and 6%, the content of conjugated olefin (double bond) in the four components increased in turn, the content of conjugated olefin(double bond) in the five fractions was about 5%,and the content of olefin(double bond) in four components and five fractions all showed a trend of decreasing first and then increasing. At the same time, there are also differences in the content of normal alpha-olefins and internal olefins between different components and different fractions.关键词
催化裂化油浆/二烯值/溴价/核磁共振/烯烃类型与分布Key words
FCC slurry/diene value/bromine number/1 H-NMR/olefin type and distribution分类
能源科技引用本文复制引用
郭爱军,郑文林,焦守辉,陈坤,刘贺,王宗贤,王子豪..催化裂化油浆中烯烃分布研究[J].燃料化学学报,2018,46(4):413-418,6.基金项目
The project was supported by the National Natural Science Foundation of China(21776313),the Provincial Key Research and Development Plan of Shandong(2017GGX70108)and the State Key Laboratory of Heavy Oil Processing(SLKZZ-2017011).国家自然科学基金(21776313),山东省重点研发计划(2017GGX70108)和重质油国家重点实验室项目(SLKZZ-2017011)资助 (21776313)