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六苯氧基环三磷腈对PA6阻燃性能的影响

周旺 龙丽娟 于杰

塑料科技2018,Vol.46Issue(3):129-133,5.
塑料科技2018,Vol.46Issue(3):129-133,5.DOI:10.15925/j.cnki.issn1005-3360.2018.03.022

六苯氧基环三磷腈对PA6阻燃性能的影响

Effect of Hexaphenoxycyclotriphosphazene as Flame Retardant on PA6

周旺 1龙丽娟 2于杰3

作者信息

  • 1. 贵州大学材料与冶金学院,贵州贵阳550004
  • 2. 国家复合改性聚合物材料工程技术研究中心,贵州贵阳550014
  • 折叠

摘要

Abstract

Hexphenoxycyclotriphosphazene(HPCP) was introduced into polyamide 6(PA6) as a flame retardant,and the mechanical properties,flame retardance and thermal properties of the composites were analyzed.The results show that:HPCP has a good flame retardant effect on PA6.With the increase of the amount of HPCP,the value of the limit oxygen index (LOI) is on the rise;When the amount of addition is 20%,the LOI increases from 26% of pure PA6 to 31%,the vertical combustion test (UL 94) also reaches V-0 level,and effectively inhibits the drop of PA6.Compared with pure PA6,the peak heat release rate (PHRR) is obviously reduced.Through the scanning electron microscopy (SEM) analysis of (TG) and remnants,the HPCP causes the PA6 to be charcoal,which inhibits its combustion and achieves the effect of flame retardant.

关键词

六苯氧基环三磷腈/聚酰胺6/阻燃

Key words

Hexphenoxycyclotriphosphazene/PA6/Flame retardant

分类

化学化工

引用本文复制引用

周旺,龙丽娟,于杰..六苯氧基环三磷腈对PA6阻燃性能的影响[J].塑料科技,2018,46(3):129-133,5.

基金项目

国家自然科学基金(No.51463006) (No.51463006)

贵州省工业攻关(黔科合GZ字[2015]3008) (黔科合GZ字[2015]3008)

塑料科技

OA北大核心CSTPCD

1005-3360

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