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首页|期刊导航|山西大学学报(自然科学版)|一种能够发射红光的氟硼二吡咯衍生物及光物理性质研究

一种能够发射红光的氟硼二吡咯衍生物及光物理性质研究

任列香 刘金 刘斌 王晓菊

山西大学学报(自然科学版)2018,Vol.41Issue(1):177-181,5.
山西大学学报(自然科学版)2018,Vol.41Issue(1):177-181,5.DOI:10.13451/j.cnki.shanxi.univ(nat.sci.).2018.01.019

一种能够发射红光的氟硼二吡咯衍生物及光物理性质研究

Synthesis and Photophysics Properties Research of a Red-Emitting Fluoroboronopyrrole Derivatives

任列香 1刘金 1刘斌 2王晓菊2

作者信息

  • 1. 吕梁学院化学化工系,山西离石033000
  • 2. 山西大学分子科学研究所,山西太原030006
  • 折叠

摘要

Abstract

In order to obtain a red-emitting material with high luminous efficiency,a new type of red-emitting fluoroboronopyrrole derivatives (Bodipy-OCH3) was successfully synthesized and characterized.The photophysical properties were studied by UV absorption technique and fluorescence emission technique,and the electron transport capacity was studied by the interaction with electron donor DMA and electron acceptor DMTP.The thermogravimetric analysis indicated the decomposition temperature was at 235 ℃.In addition,the energy structure and electron cloud distribution of the compound were further analyzed by Gaussian 09 software and electrochemistry.

关键词

红光材料/电子传输/热稳定性/理论计算

Key words

red-emitting materials/electronic transmission/thermal stability/theoretical calculation

分类

化学化工

引用本文复制引用

任列香,刘金,刘斌,王晓菊..一种能够发射红光的氟硼二吡咯衍生物及光物理性质研究[J].山西大学学报(自然科学版),2018,41(1):177-181,5.

基金项目

国家自然科学基金(21271122) (21271122)

吕梁学院科研基金(ZRXN201412) (ZRXN201412)

山西大学学报(自然科学版)

OA北大核心CSTPCD

0253-2395

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