苏州科技大学学报（自然科学版）2018，Vol.35Issue(1)：62-66,5.DOI:10.12084/j.issn.2096-3289.2018.01.012
介孔四氧化三钴的制备及电催化水析氧研究
Preparation of mesoporous Co3O4 and water electrocatalytic oxidation evolution
徐孝文 1王艳 1曹敏1
作者信息
- 1. 苏州科技大学 化学生物与材料工程学院,江苏 苏州215009
- 折叠
摘要
Abstract
Mesoporous Co3O4 was prepared by using CoCl2·6H2O and(NH4)6Mo7O24·4H2O as raw materials via a solution method of electrostatic self-assembly and calcinations, and dissolving Co 3O4/MoO3 with NaOH solution. X-ray diffraction(XRD),transmission electron microscopy(TEM)and surface area and porosity analyzer(AS-AP)were used for characterization of mesoporous Co3O4. It has a high surface area of 127.4 m2·g-1and a meso-porous structure with a pore diameter of 10-20 nm. The catalytic performance for H2O electro-oxidation in KOH solution was evaluated by means of linear scan voltammetre.The catalyst presents good activities of a low onset of~0.392 V(vs.Ag/AgCl)in 1 mol·L-1KOH at a scan rate of 5 mV·s-1 for water oxidation.关键词
介孔材料/四氧化三钴/电催化氧化/析氧Key words
mesoporous materials/Co3O4/electrocatalytic oxidation/oxygen evolution分类
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徐孝文,王艳,曹敏..介孔四氧化三钴的制备及电催化水析氧研究[J].苏州科技大学学报（自然科学版）,2018,35(1):62-66,5.
