无机材料学报2018，Vol.33Issue(3)：289-294,6.DOI:10.15541/jim20170181
表面活性剂对NiCo2S4纳米薄膜的电化学性能影响的研究
Surfactant Dependence of Nanostructured NiCo2S4Films on Ni Foam for Superior Electrochemical Performance
张国雄 1陈月梅 1何臻妮 1林川 2陈益钢 1郭海波1
作者信息
- 1. 上海大学 材料科学与工程学院,上海 200444
- 2. GE全球研发中心,上海 201203
- 折叠
摘要
Abstract
Nanostructured NiCo2S4films on Ni foams were successfully synthesized through a facile method, involv-ing hydrothermal growth of NiCo-precursor and subsequent sulfidation process of NiCo2S4. The influence of different surfactants were investigated, including morphology, phase structure and electrochemical performance of NiCo2S4 electrodes. With the addition of surfactants during the hydrothermal processes, the nanostructured NiCo2S4self-organized and agglomerated into nanosheets, showing outstanding influence on the morphology by the surfactants. Among these electrodes, the NiCo2S4electrode modified with SDS exhibited an optimal capacitance of 2893 F/g at 0.5 A/g, a superior rate capability of 1890.6 F/g even at 10 A/g, and good cycling stability of 96.1% over 1000 cycles. These results indicate that nanosheet NiCo2S4would be promising electrode materials for supercapacitor applications.关键词
纳米结构NiCo2S4/表面活性剂/水热法/电化学性能Key words
nanostructured NiCo2S4/surfactants/hydrothermal/electrochemical performance分类
化学化工引用本文复制引用
张国雄,陈月梅,何臻妮,林川,陈益钢,郭海波..表面活性剂对NiCo2S4纳米薄膜的电化学性能影响的研究[J].无机材料学报,2018,33(3):289-294,6.
