无机材料学报2018，Vol.33Issue(3)：307-312,6.DOI:10.15541/jim20170169
半空心/实心ZnMn2O4微球:合成及锂离子电池性能
Semi-hollow/Solid ZnMn2O4Microspheres: Synthesis and Performance in Li Ion Battery
摘要
Abstract
Porous semi-hollow/solid ZnMn2O4microspheres were controllably synthesized via template and sol-vothermal methods respectively. The as-synthesized samples were characterized by X-ray diffraction (XRD), scan-ning electron microscope (SEM) and transmission electron microscope (TEM). It is found that the solvent ratio ex-erts a crucial effect on the morphology and microstructure of solid ZnMn2O4microspheres. The porous solid ZnMn2O4microspheres could be obtained when the volume ratio of ethylene glycol to deionized water was 3 : 1. The semi-hollow ZnMn2O4microspheres with a double-layer ZnMn2O4shell and a small C core could be synthe-sized via a template-solvothermal method and post-calcination process. The electrochemical properties of as-prepared semi-hollow/solid ZnMn2O4microspheres as anode materials of lithium-ion batteries were investigated. Semi-hollow ZnMn2O4microspheres exhibit higher initial discharge capacity, better rate capacity and cycling per-formance than solid ZnMn2O4microspheres.关键词
ZnMn2O4/空心微球/多孔材料/锂离子电池Key words
ZnMn2O4/hollow microsphere/porous materials/lithium-ion battery分类
化学化工引用本文复制引用
李波,郝文,文晓刚..半空心/实心ZnMn2O4微球:合成及锂离子电池性能[J].无机材料学报,2018,33(3):307-312,6.基金项目
国家自然科学基金(50872084,51072124)National Natural Science Foundation of China(50872084,51072124) （50872084,51072124）
