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静电纺聚碳硅烷制备SiOC超细纤维

吴楠 WAN Lynn Yuqin 王应德 FRANK KO

无机材料学报2018,Vol.33Issue(3):357-362,6.
无机材料学报2018,Vol.33Issue(3):357-362,6.DOI:10.15541/jim20170153

静电纺聚碳硅烷制备SiOC超细纤维

Electrospun Silicon Oxycarbide Ultrafine Fibers Derived from Polycarbosilane

吴楠 1WAN Lynn Yuqin 2王应德 2FRANK KO1

作者信息

  • 1. 国防科技大学新型陶瓷纤维及其复合材料重点实验室,长沙 410073
  • 2. 不列颠哥伦比亚大学材料工程系,温哥华 V6T 1Z4
  • 折叠

摘要

Abstract

Silicon oxycarbide(SiOC)ultrafine fibers with uniform distribution were prepared via electrospinning of polycarbosilane (PCS)/polystyrene followed by oxidation and pyrolysis at 1100℃. The diameter of SiOC fibers ranged from 500 to 900 nm through adjusting PCS concentration. The average tensile strength of SiOC fiber mat was 8.88 MPa. The obtained SiOC fibers also displayed outstanding thermal stability and chemical resistance, making them promising materials as smart filters and catalyst supports in harsh environment.

关键词

静电纺丝/聚碳硅烷/硅氧碳/陶瓷纤维

Key words

electrospinning/polycarbosilane/silicon oxycarbide/ceramic fibers

分类

化学化工

引用本文复制引用

吴楠,WAN Lynn Yuqin,王应德,FRANK KO..静电纺聚碳硅烷制备SiOC超细纤维[J].无机材料学报,2018,33(3):357-362,6.

基金项目

National Natural Science Foundation of China (51173202) (51173202)

无机材料学报

OA北大核心CSCDCSTPCDSCI

1000-324X

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