西安石油大学学报（自然科学版）2018，Vol.33Issue(2)：82-93,12.DOI:10.3969/j.issn.1673-064X.2018.02.013
后过渡金属催化剂催化甲基丙烯酸甲酯聚合的研究进展
Progress in Research of Late-Transition Metal Catalysts for Polymerization of Methyl Methacrylate
摘要
Abstract
The progress in the research of late-transition metal catalysts for the polymerization of methyl methacrylate was reviewed, mainly including the metal complex catalysts of nickel system,copper system,iron system and cobalt system.Their catalytic activity of various kinds of catalysts,the relative molecular mass and microstructure of the prepared poly-methyl methacrylates and the distribution of the relative molecular mass are compared.It was proposed that the introduction of electron-withdrawing group to the structure of cata-lysts is necessary to improving their catalytic activity,and the further research of the structure of catalysts to effectively control the mi-crostructure of Poly(methyl methacrylate)is one of the future research directions for the polymerization of methyl methacrylate.关键词
后过渡金属/催化剂/甲基丙烯酸甲酯/聚合Key words
late-transition metal/catalyst/methyl methacrylate(MMA)/polymerization分类
化学化工引用本文复制引用
丁丽芹,陈晓洛,李孟阁,刘雪梅..后过渡金属催化剂催化甲基丙烯酸甲酯聚合的研究进展[J].西安石油大学学报（自然科学版）,2018,33(2):82-93,12.基金项目
陕西省自然科学基础研究计划资助项目"富含间规聚苯乙烯的新型Cu、Ni系催化剂开发"(2013JQ2002) （2013JQ2002）
陕西省自然科学基础研究计划资助项目"新型过氧钼酸盐的合成及催化性能研究"(2016JQ2037) （2016JQ2037）
