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二烯丙基双酚A对低黏度氰酸酯树脂的改性研究

蒋佩琪 肖军 李金焕 韩晓艳

玻璃钢/复合材料Issue(3):58-62,5.
玻璃钢/复合材料Issue(3):58-62,5.

二烯丙基双酚A对低黏度氰酸酯树脂的改性研究

STUDY ON THE MODIFICATION OF DIALLYL BISPHENOL A TO CYANATE ESTER RESIN WITH LOW VISCOSITY

蒋佩琪 1肖军 1李金焕 1韩晓艳1

作者信息

  • 1. 南京航空航天大学材料科学与技术学院,南京 210016
  • 折叠

摘要

Abstract

The modification of dimly lbisphenol A (DBA) to low viscosity cyanate ester resin was investigated by the test of viscosity-temperature characteristics,differential scanning calorimetry,mechanical test,thermal gravimetric analysis,dynamic thermomechanical analysis,water absorption and dielectric performance.The results show that the viscosity of CE modified by DBA slightly increased,but it still satisfied the viscosity requirement for hot melt method.DBA can catalyze the curing reaction of CE and increase the conversion ratio.DBA of appropriate amount can toughen the cured resin,the impact strength and flexural toughness of the resin with 10% DBA were 179% and 165% times higher than those of the unmodified resin,respectively.The heat resistance,moisture resistance and dielectric property of CE modified by DBA all decreased slightly compared with the unmodified,but still met the application requirements.It is concluded that the optimum addition of DBA is 5% ~ 10%.

关键词

二烯丙基双酚A/低黏度/氰酸酯树脂/改性

Key words

diallyl bisphenol A/low viscosity/cyanate ester resin/modification

分类

通用工业技术

引用本文复制引用

蒋佩琪,肖军,李金焕,韩晓艳..二烯丙基双酚A对低黏度氰酸酯树脂的改性研究[J].玻璃钢/复合材料,2018,(3):58-62,5.

基金项目

国家“973”计划(2014CB046501) (2014CB046501)

江西高校优势学科建设工程项目 ()

玻璃钢/复合材料

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