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包覆改性对高电压钴酸锂微观组织与性能的影响

李春流 闫冠杰 卢道焕 周文政 黎光旭

电源技术2018,Vol.42Issue(3):324-325,360,3.
电源技术2018,Vol.42Issue(3):324-325,360,3.

包覆改性对高电压钴酸锂微观组织与性能的影响

Effect of coating modification on microstructure and properties of high voltage LiCoO2

李春流 1闫冠杰 1卢道焕 1周文政 1黎光旭2

作者信息

  • 1. 中信大锰矿业有限责任公司,广西南宁530028
  • 2. 广西大学物理科学与工程技术学院广西高校新能源材料及相关技术重点实验室,广西南宁530004
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摘要

Abstract

Coating modification is an important research direction of the lithium cobalt oxide (LiCoO2) cathode materials.Using solid phase sintering method,LiCoO2 was coated with nanometer titanium dioxide,aluminum hydroxide and magnesium hydroxide under different conditions.Electrochemical measurements were performed at 0.5 C and 1 C,in the range of 3.0-4.35 V.The specific capacity,platform rate and cycle performance of composite coating modified LiCoO2 were improved obviously.The best electrochemical performance of coated modified LiCoO2 was obtained at 980 ℃/12 h.The specific capacity was up to 172.8 mAh/g,and after 1 00 cycles,the capacity decay was only 6.2%.

关键词

钴酸锂/高电压/包覆改性/固相烧结

Key words

lithium cobalt oxide/high voltage/coating modification/solid phase sintering

分类

信息技术与安全科学

引用本文复制引用

李春流,闫冠杰,卢道焕,周文政,黎光旭..包覆改性对高电压钴酸锂微观组织与性能的影响[J].电源技术,2018,42(3):324-325,360,3.

基金项目

国家自然科学基金(61264006) (61264006)

广西自然科学基金(2014GXNSFAA118340) (2014GXNSFAA118340)

广西自然科学基金杰出青年基金(2013-GXNSFGA019007) (2013-GXNSFGA019007)

电源技术

OA北大核心CSTPCD

1002-087X

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