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锂离子电池用SiO/C负极材料的制备及性能研究

夏文明 唐仁衡 王英 肖方明 王辉

电源技术2018,Vol.42Issue(3):329-332,4.
电源技术2018,Vol.42Issue(3):329-332,4.

锂离子电池用SiO/C负极材料的制备及性能研究

Preparation of SiO/C anode materials for Li-ion batteries and its performance

夏文明 1唐仁衡 2王英 3肖方明 4王辉1

作者信息

  • 1. 广东省稀有金属研究所,广东广州510651
  • 2. 广东省稀土开发及应用重点实验室,广东广州510651
  • 3. 华南理工大学材料科学与工程学院,广东广州510641
  • 4. 广东省先进储能材料国家重点实验室,广东广州510641
  • 折叠

摘要

Abstract

The SiO/C composites were prepared by mechanical ball-milling,spray drying and high-temperature pyrolysis technology,using asphalte,citric acid and sucrose as carbon sources.The microstructure and morphology of the prepared SiO/C composites by different carbon sources were characterized by XRD,TG and SEM.The test results demonstrate that the carbon content of SiO/C composite using asphalt,citric acid,sucroce are 15.8%,14.1%,9.7%,respectively.The electrochemical tests result show that the coulombic efficiency of SiO/C composites using asphalte,citric acid and sucrose as carbon sources are 62.7%,54.6% and 53.6%,respectively.After 100 discharge/charge cycles,the discharge specific capacity are 661.7,565.1 and 322.8 mAh/g,respectively.This implies the SiO/C composite by asphalt exhibits the best electrochemical performances,and the enhanced electrochemical performances are attributed to the most amorphous carbon content.

关键词

锂离子电池/沥青/柠檬酸/蔗糖/SiO/C负极材料

Key words

lithium-ion batteries/asphalt/citric acid/sucroce/SiO/C anode material

分类

信息技术与安全科学

引用本文复制引用

夏文明,唐仁衡,王英,肖方明,王辉..锂离子电池用SiO/C负极材料的制备及性能研究[J].电源技术,2018,42(3):329-332,4.

基金项目

广东省省级科技计划项目(2015B010116002) (2015B010116002)

广东省自然科学基金(2014A030308015) (2014A030308015)

电源技术

OA北大核心CSTPCD

1002-087X

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