硅酸盐通报2018，Vol.37Issue(2)：596-601,6.
ZnO对黄磷炉渣微晶玻璃析晶影响
Effect of ZnO on Crystallization of Glass-ceramics from Yellow Phosphorus Furnace Slag
摘要
Abstract
A series of CaO-Al2O3-SiO2 glass-ceramics were prepared by melting method using yellow phosphorus furnace slag as the main raw material and adding different amount of zinc oxide.The crystallization activation energy was calculated using Kissinger equation.The crystal phase composition was calculated by FactSage 6.4.The results of simulation and calculation were proved by means of X-ray diffraction and scanning electron microscopy.The results show that temperature of crystallization peak and the crystallization activation energy of basic glass gradually decrease with the increasing of zinc oxide content.When adding 7wt％ zinc oxide,the crystallization activation energy of basic glass is minimum.The predominant crystalline phase is wollastonite(CaSiO3) and the minor crystalline phases is aluminian diopside(Ca (Mg,Al)(Si,Al)2O6)and it doesn't change with the increase of zinc oxide content.It is consistent with FactSage 6.4 calculation results.关键词
黄磷炉渣/ZnO/FactSage/析晶动力学/微晶玻璃Key words
yellow phosphorus furnace slag/ZnO/FactSage/crystallization kinetic/glass-ceramic分类
化学化工引用本文复制引用
尚志标,黄小凤,马丽萍,刘红盼,陈丹莉,刘秀状,赵丹,范莹莹..ZnO对黄磷炉渣微晶玻璃析晶影响[J].硅酸盐通报,2018,37(2):596-601,6.基金项目
昆明理工大学校测试基金(2017M20152207032,2017M20162107015) （2017M20152207032,2017M20162107015）
