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C/C-Cu复合材料的烧蚀形貌和烧蚀机理

孙乐 王成 宗彦旭 吴坤尧 丁旭

宇航材料工艺2018,Vol.48Issue(2):25-28,4.
宇航材料工艺2018,Vol.48Issue(2):25-28,4.DOI:10.12044/j.issn.1007-2330.2018.02.005

C/C-Cu复合材料的烧蚀形貌和烧蚀机理

Ablative Morphology and Mechanism in Different Regions of C/C-Cu Composites

孙乐 1王成 2宗彦旭 1吴坤尧 1丁旭1

作者信息

  • 1. 西安航空学院材料工程学院,西安710077
  • 2. 西安航空学院新材料研究所,西安710077
  • 折叠

摘要

Abstract

Using PAN-based pre-oxidized fiber integral felt as reinforcement,the porous C/C preforms were fabricated by carbonization and isothermal CVI,and then C/C-Cu composites were manufactured by gas pressure infiltration technique which introduced copper into the porosity of C/C preforms.The ablative properties of C/C-Cu composites were tested by H2-O2 ablation method.The micro-morphology and constitutions in different ablative regions were analyzed by SEM and EDS.The results indicate that the ablative performance of C/C-Cu composites with 0.96g/cm3density is excellent due to low linear and mass ablation rate.The ablative macro-morphology is composed of significant pit as central region in which the ablative mechanisms are oxidation of C/C preform and mechanical erosion of copper.Thermal oxidation and mechanical erosion of copper result in copper concentration in transition region,and black color surface in marginal region is due to oxidation of C/C preform.In order to improve the ablative performance of C/C-Cu,"pinning" effect of C/C preform should play an important role which can prevent copper from flowing by flame at high temperature.

关键词

C/C-Cu/烧蚀/氧化/机械冲刷/钉扎效应

Key words

C/C-Cu composites/Ablation/Oxidation/Mechanical erosion/Pinning effect

分类

通用工业技术

引用本文复制引用

孙乐,王成,宗彦旭,吴坤尧,丁旭..C/C-Cu复合材料的烧蚀形貌和烧蚀机理[J].宇航材料工艺,2018,48(2):25-28,4.

基金项目

国家级大学生创新创业训练计划项目(201611736001) (201611736001)

宇航材料工艺

OA北大核心CSCDCSTPCD

1007-2330

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