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近紫外光激发KBaGd(MoO4)3∶Dy3+荧光粉的制备及发光性能

宋明君 王林同 张娜娜 任仰 李丹

发光学报2018,Vol.39Issue(3):259-265,7.
发光学报2018,Vol.39Issue(3):259-265,7.DOI:10.3788/fgxb20183903.0259

近紫外光激发KBaGd(MoO4)3∶Dy3+荧光粉的制备及发光性能

Preparation and Luminescent Properties of Near UV Excited KBaGd(MoO4)3:Dy3+Phosphors

宋明君 1王林同 1张娜娜 1任仰 1李丹1

作者信息

  • 1. 潍坊学院 化学化工学院,山东 潍坊 261061
  • 折叠

摘要

Abstract

KBaGd(MoO4)3:Dy3+phosphors were synthesized by sol-gel method,and their morphol-ogy,structure and spectral properties were investigated by means of SEM,XRD,excitation and lu-minescent spectra,as well as luminescent decay curves. The results show that the shape and the particle size distribution of samples synthesized by sol-gel method are more regular and narrower than those synthesized by solid state method. Under the excitation of near UV light(390 nm),the sam-ples exhibit two intensive emission bands around 485 nm and 577 nm,and the value of B/Y is about 0.7. In the host of KBaGd(MoO4)3,the optimum mole fraction of Dy3+is 10%, and the concen-tration quenching effect is caused by dipole-dipole interactions between Dy3+ions. The luminescent lifetime becomes shorter and the decay curves become nonexponential with the increasing of Dy3+concentration.

关键词

钼酸盐/荧光粉/浓度猝灭/色坐标

Key words

molybdate/phosphors/concentration quenching/color coordinate

分类

数理科学

引用本文复制引用

宋明君,王林同,张娜娜,任仰,李丹..近紫外光激发KBaGd(MoO4)3∶Dy3+荧光粉的制备及发光性能[J].发光学报,2018,39(3):259-265,7.

基金项目

国家自然科学基金(51541205) (51541205)

山东省自然科学基金(ZR2014JL029,ZR2016BQ40,ZR2017BEE038)资助项目 Supported by National Natural Science Foundation of China(51541205) (ZR2014JL029,ZR2016BQ40,ZR2017BEE038)

Natural Science Foundation of Shandong Province(ZR2014JL029,ZR2016BQ40,ZR2017BEE038) (ZR2014JL029,ZR2016BQ40,ZR2017BEE038)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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