发光学报2018,Vol.39Issue(3):307-314,8.DOI:10.3788/fgxb20183903.0307
金属离子Li+,Na+,K+,Ca2+,Ba2+掺杂Lu2O3∶Pr3+荧光粉的制备及发光特性研究
Preparation and Luminescence Properties of Lu2O3:Pr3+Phosphors Codoped with Li+, Na+, K+, Ca2+, Ba2+Ions
摘要
Abstract
Lu2O3:xPr3+and Lu2O3:0.1% Pr3+,yM(M=Li+,Na+,K+,Ca2+,Ba2+) phosphors were synthesized by the high temperature solid-state reaction. The structures of the samples were characterized by XRD, the excitation spectra, emission spectra and luminescence decay curves of the samples were measured. The influences of the doping metal ions of Li+, Na+, K+, Ca2+and Ba2+on the microstructure,luminescence intensity and fluorescence lifetime for synthesized samples of Lu2O3:Pr3+were researched. The results show that the samples after doping metal ions are still pure Lu2O3cubic crystal phase structure. The emission intensities of Lu2O3:0.1% Pr3+samples doped with 12% Li+,8% Na+and 8% K+increased 7.32,4.11 and 2.55 times than that of Lu2O3:0.1% Pr3+sample, but the emission intensities of samples doped with Ca2+and Ba2+decreased. Compared with 1D2fluorescence lifetime of Lu2O3: 0.1% Pr3+sample, the lifetime of the samples codoped with Li+,Na+,K+,Ca2+,Ba2+all decreased.关键词
荧光粉/金属离子掺杂Lu2O3∶Pr3+/发光强度/荧光寿命Key words
phosphor/Lu2O3:Pr3+codoped with the metal ions/luminous intensity/fluorescence lifetime分类
数理科学引用本文复制引用
庹娟,王林香,叶颖,赵海琴..金属离子Li+,Na+,K+,Ca2+,Ba2+掺杂Lu2O3∶Pr3+荧光粉的制备及发光特性研究[J].发光学报,2018,39(3):307-314,8.基金项目
新疆维吾尔自治区自然科学基金(2017D01A60) (2017D01A60)
新疆师范大学新疆矿物发光材料及其微结构重点实验室招标课题(KWFG1601,KWFG1606) (KWFG1601,KWFG1606)
新疆师范大学硕士研究生科技创新项目(XSY201602008) (XSY201602008)
新疆师范大学本科生科技创新项目(201610762098)资助 Supported by Natural Science Foundation of Xinjiang(2017D01A60) (201610762098)
Foundation of Key Laboratory of Mineral and Microstruc-ture of Xinjiang(KWFG1601,KWFG1606) (KWFG1601,KWFG1606)
Xinjiang Normal University Graduate Student Science and Technology Innovation Project(XSY201602008) (XSY201602008)
Xinjiang Normal University Undergraduate Science and Technology Innovation Project(201610762098) (201610762098)