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聚苯乙烯荧光乳液的制备及其性能研究

吕彤 张光华 郭明媛

发光学报2018,Vol.39Issue(4):466-474,9.
发光学报2018,Vol.39Issue(4):466-474,9.DOI:10.3788/fgxb20183904.0466

聚苯乙烯荧光乳液的制备及其性能研究

Preparation of Polystyrene Fluorescent Emulsion and Its Properties

吕彤 1张光华 1郭明媛1

作者信息

  • 1. 陕西科技大学 教育部轻化工助剂化学与技术重点实验室,陕西 西安 710021
  • 折叠

摘要

Abstract

In order to improve the water solubility of naphthalimide and the combination with the paper, the polystyrene fluorescent emulsion was prepared by emulsion polymerization,and its synthesis condi-tions were optimized. The structure was determined by FT-IR and gel permeation chromatography (GPC). The optical properties were measured by UV and fluorescence spectra. Its morphology was ob-served by scanning electron microscopy and transmission electron microscopy. The fluorescence quantum yield is 78.57%. After polymer coats on the surface of the paper, its initial whiteness increases by 8.19%(ISO). After 48 h UV light irradiation, compared with that of the blank paper and the paper which coats the micromolecule fluorescent whitening agent,the whiteness of the paper which coats the polymer decreases by 3.68%(ISO) and 3.16%(ISO),respectively. The results show that the prepared polymer emulsion and paper adhesion are good,with whitening and yellowing inhibition.

关键词

荧光增白剂/萘酰亚胺/苯乙烯/聚合物乳液稳定性

Key words

yellowing inhibitor/naphthalimide/styrene/stability of polymer emulsion

分类

数理科学

引用本文复制引用

吕彤,张光华,郭明媛..聚苯乙烯荧光乳液的制备及其性能研究[J].发光学报,2018,39(4):466-474,9.

基金项目

国家自然科学基金(31670596)资助项目Supported by National Natural Science Foundation of China(31670596) (31670596)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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