发光学报2018,Vol.39Issue(4):466-474,9.DOI:10.3788/fgxb20183904.0466
聚苯乙烯荧光乳液的制备及其性能研究
Preparation of Polystyrene Fluorescent Emulsion and Its Properties
摘要
Abstract
In order to improve the water solubility of naphthalimide and the combination with the paper, the polystyrene fluorescent emulsion was prepared by emulsion polymerization,and its synthesis condi-tions were optimized. The structure was determined by FT-IR and gel permeation chromatography (GPC). The optical properties were measured by UV and fluorescence spectra. Its morphology was ob-served by scanning electron microscopy and transmission electron microscopy. The fluorescence quantum yield is 78.57%. After polymer coats on the surface of the paper, its initial whiteness increases by 8.19%(ISO). After 48 h UV light irradiation, compared with that of the blank paper and the paper which coats the micromolecule fluorescent whitening agent,the whiteness of the paper which coats the polymer decreases by 3.68%(ISO) and 3.16%(ISO),respectively. The results show that the prepared polymer emulsion and paper adhesion are good,with whitening and yellowing inhibition.关键词
荧光增白剂/萘酰亚胺/苯乙烯/聚合物乳液稳定性Key words
yellowing inhibitor/naphthalimide/styrene/stability of polymer emulsion分类
数理科学引用本文复制引用
吕彤,张光华,郭明媛..聚苯乙烯荧光乳液的制备及其性能研究[J].发光学报,2018,39(4):466-474,9.基金项目
国家自然科学基金(31670596)资助项目Supported by National Natural Science Foundation of China(31670596) (31670596)