化工进展2018,Vol.37Issue(5):1804-1814,11.DOI:10.16085/j.issn.1000-6613.2017-0539
氧化铈基HCl氧化循环制Cl2催化剂研究进展
Research progress in recycle oxidation of HCl to Cl2over ceria based catalysts
摘要
Abstract
The catalytic oxidation of HCl is gaining increasing application and industrial prospects in the chlorine-related industry. CeO2-based materials have been regarded as the most promising catalysts for HCl oxidation due to their excellent characteristics such as low-cost,sintering-resistant and anti-chlorination. After a brief introduction of the chlorine circulation process,this manuscript discusses different ceria-based catalytic materials for HCl catalyzed oxidation,including CeO2 catalyst,modified CeO2catalyst and CeO2as catalyst promoter. Special focus has been put on the surface reaction mechanism of HCl oxidation on CeO2. Considering the current research condition,this review also provides some future prospects for promoting the activity of CeO2-based catalysts in HCl oxidation.关键词
催化/氧化/氯循环/氧化铈/氯气Key words
catalysis/oxidation/chlorine circulation/cerium oxide(CeO2)/chlorine分类
化学化工引用本文复制引用
楼家伟,费兆阳,刘清,陈献,汤吉海,崔咪芬,张竹修,乔旭..氧化铈基HCl氧化循环制Cl2催化剂研究进展[J].化工进展,2018,37(5):1804-1814,11.基金项目
国家自然科学基金项目(21306089). (21306089)