人工晶体学报2018，Vol.47Issue(4)：822-825,830,5.
含(1E,2E)-N1,N2-双((8-丁氧基喹啉-2-)亚甲基)乙烷-1,2-二胺的双核银配合物的合成与晶体结构
Synthesis and Crystal Structures of Dinuclear Ag(I)Complex Comprising(1E,2E)-N1,N2-bis((8-butoxyquinolin-2-yl)methylene)ethane-1,2-diamine
摘要
Abstract
IA dinuclear Ag(I)Complex containing the ligand of(1E,2E)-N1,N2-bis((8-butoxyquinolin-2-yl)methylene)ethane-1,2-diamine was synthesized and characterized by 1 H NMR, sing-crystal diffraction.The crystal of complex I crystallizes in triclinic,space group P-1 with a=13.489(5)?,b=13.550(5)?,and c=19.836(8)?,α=70.077(6)°, β=75.145(9)°and γ=82.430(6)°, V=3291(2)?3, Z =2, C60H68Ag2F12N8O5P2, Mr=1486.90, Dx=1.500 g/cm3, T =296(2)K. Structure determination shows that the 8-hydroxyquinoline derivative acts as quadridentate ligand to link two Ag(I).The 8-hydroxyquinoline derivative and complex I show similar photoluminescent spectra in diluted acetonitrile solution(1×10 -6mol· L-1)at room temperature.关键词
双核银配合物/8-羟基喹啉衍生物/晶体结构Key words
dinuclear Ag(I)complex/8-hydroxyquinoline derivative/crystal structure分类
数理科学引用本文复制引用
赵波,张仕禄..含(1E,2E)-N1,N2-双((8-丁氧基喹啉-2-)亚甲基)乙烷-1,2-二胺的双核银配合物的合成与晶体结构[J].人工晶体学报,2018,47(4):822-825,830,5.基金项目
Scientific and Technological Innovation Project of Sichuan(2017063) （2017063）
