太原理工大学学报2018，Vol.49Issue(3)：371-379,9.DOI:10.16355/j.cnki.issn1007-9432tyut.2018.03.001
PtRu合金催化剂电催化氧化甲醇的作用机理
Insights into Catalytic Mechanism of PtRu Alloy Catalyst for Electrically Catalyzing Methanol Oxidation
摘要
Abstract
The alloyed PtRu/C,core-shell Ru@Pt/C and Pt/C nanocomposite catalysts in similar diameter with different Pt/Ru atomic ratios were synthesized by chemical reduction meth-od.Physical characterization and electrochemical characterization results show that the diameter of Ru@Pt/C,PtRu/C nano-metal particles is about 9~1 1 nm,and Ru@Pt/C in core-shell struc-ture.The mechanism of Ru@Pt/C electrocatalytic oxidation of methanol meets the electronic effect mechanism,the mechanism of PtRu/C is consistent with the electronic effect and the bi-functional mechanism.The clarification of the catalytic mechanism provides a solid theoretical ba-sis for the development of new catalysts.关键词
PtRu/C/Ru@Pt/C/电催化氧化甲醇/电子效应/双功能机理Key words
PtRu/C/Ru@Pt/C/methanol electro-oxidation/electronic effect/bifunctional mechanism分类
化学化工引用本文复制引用
王媛媛,原沁波,卫国强,段东红,张忠林,王恩志,李瑜,郝晓刚,刘世斌..PtRu合金催化剂电催化氧化甲醇的作用机理[J].太原理工大学学报,2018,49(3):371-379,9.基金项目
国家自然科学基金资助项目(20676088) （20676088）
