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土壤中的Cr在纳米铁修复过程中的降解分离

李平 曹青 张弛 张思思

太原理工大学学报2018,Vol.49Issue(3):406-411,6.
太原理工大学学报2018,Vol.49Issue(3):406-411,6.DOI:10.16355/j.cnki.issn1007-9432tyut.2018.03.006

土壤中的Cr在纳米铁修复过程中的降解分离

Separation and Degradation State of Cr During the Process of nZVI Remediation in Soil

李平 1曹青 1张弛 2张思思2

作者信息

  • 1. 太原理工大学化学化工学院,太原030024
  • 2. 太原理工大学环境科学与工程学院,太原030024
  • 折叠

摘要

Abstract

A dynamic soil column test was conducted to study the leaching pattern between va-rious soils and Cr(total),Cr(VI)and Cr(III),under the action of nanoscale zero-valent iron and deionized water.According to the results,the concentration and accumulation of the Cr in soil under the water runoff differ in different stages of washing.The washout effect lies between 0~1.5 L chiefly.When organic matter content of the soil is high,the adsorption effect on Cr(total) is enhanced,and the concentration of Cr(total)increases slowly.When the organic matter con-tent increases from 0.24% to 11.40%,the total amount of Cr(total)that is washed out by nZVI decreases by 0.716 mg at 2 L.For the soil with organic content of 0.24%~11.40%,the nZVI reaction system has good treatment effect on Cr(VI)contaminated soil.In this paper,R1.5and R6 values are used to define the proportion of the accumulation amount of the washout Cr(total)to the starting Cr within the typical range.With the Cr (III)index of apparent adsorption amount, the degradation and separation state of the Cr(VI)in the washout process is quantitatively de-fined.The research result in this paper has an important reference value for soil heavy metal treatment technology.

关键词

土壤//纳米零价铁/还原/吸附

Key words

soil/chromium/nano zero valent iron/reduction/adsorption

分类

资源环境

引用本文复制引用

李平,曹青,张弛,张思思..土壤中的Cr在纳米铁修复过程中的降解分离[J].太原理工大学学报,2018,49(3):406-411,6.

基金项目

山西省重点研发计划(20150313002-2,201703D321005) (20150313002-2,201703D321005)

太原理工大学学报

OA北大核心CSTPCD

1007-9432

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