化工进展2018，Vol.37Issue(6)：2031-2045,15.DOI:10.16085/j.issn.1000-6613.2017-2249
金属卟啉催化氧化环己烷最新研究进展
Recent advances in the oxidation of cyclohexane catalyzed by metalloporphyrins
摘要
Abstract
Recent advances in catalytic oxidation of cyclohexane have been reviewed in detail,including the catalytic systems employing PhIO,PhI(OAc)2,O2,t-BuOOH,NaIO4and H2O2as the oxidants. It is pointed out that the development of heterogeneous catalytic system employing O2as oxidant with high activity and selectivity will be the focus of oxidation of cyclohexane catalyzed by metalloporphyrin in the future,especially for the metalloporphyrin systems with multi metals. The metalloporphyrin with high catalytic performance both in activation of O2and in decomposition and transformation of cyclohexyl hydrogen peroxide through covalent bond to construct metalloporphyrin system with multi metals will increase the conversion of cyclohexane and the selectivity of oxidation product. This review can act as an important reference in the research and development of the catalytic system for the cyclohexane oxidation as well as other hydrocarbon oxidation and non-hydrocarbon oxidation.关键词
烷烃/金属卟啉/仿生催化/氧化Key words
alkane/metalloporphyrin/biomimetic catalysis/oxidation分类
化学化工引用本文复制引用
沈海民,王岩,佘远斌..金属卟啉催化氧化环己烷最新研究进展[J].化工进展,2018,37(6):2031-2045,15.基金项目
国家自然科学基金项目(21476270,21306176,21776259). （21476270,21306176,21776259）
