化工进展2018，Vol.37Issue(6)：2077-2083,7.DOI:10.16085/j.issn.1000-6613.2017-1682
基于适应策略差分进化算法的化工反应动力学参数估值
Differential evolution using adaptive strategy for parameter estimation of chemical reaction kinetics
摘要
Abstract
To better predict the percentage of mercury oxidized based on the concentrations of other flue gas components,an accurate kinetic model for Hg oxidation needs to be developed. The existing models always contain some unknown parameters that are difficult to identify. To extract these parameters exactly and fast,this paper puts forward an adaptive strategy based on differential evolution (ASDE). The new ASDE contains candidate set for mutation strategy,scale factor(F)and crossover rate(CR). Each value in every candidate set has its own selection probability and the selection probability is updated according to the previous search information. Based on the selection probability, an adaptive model is designed to set the most proper control parameters for every vector in the main population. The ASDE is applied to solve parameter estimation problem of Hg oxidation models. The experimental results showed that ASDE is able to obtain more accurate model than other 6 algorithms. It is an effective approach for parameter estimation of chemical reaction kinetics.关键词
差分进化/适应性策略/优化/反应动力学/参数估值Key words
differential evolution/adaptive strategy/optimization/reaction kinetics/parameter estimation分类
信息技术与安全科学引用本文复制引用
徐斌,陈旭,陶莉莉,张海峰..基于适应策略差分进化算法的化工反应动力学参数估值[J].化工进展,2018,37(6):2077-2083,7.基金项目
国家自然科学基金(61703268)、中央高校基本科研业务费重点科研基地创新基金(222201717006)、上海高校青年教师培养资助计划(ZZgcd14002)及江苏省自然科学基金(BK20160540)项目. （61703268）
