石油化工2018，Vol.47Issue(5)：486-492,7.DOI:10.3969/j.issn.1000-8144.2018.05.015
乙烯基单体改性水性聚氨酯的合成及其用于烟包印刷用光油
Synthesis of vinyl monomers modified waterborne polyurethane and its application as gloss oil used in cigarette package printing
摘要
Abstract
A series of environment-friendly composite materials of vinyl monomers modified waterborne polyurethane(WPUA) with high stability and no triethylamine are prepared by using high temperature-resistant polyester polyol and 4,4′-methylenebis(cyclohexyl isocyanate) as main raw materials,which are copolymerized with different vinyl monomers respectively. The structures and properties of WPUA emulsions and films were characterized by FTIR,TEM,TG,DSC and XRD. And the performance of waterborne colored paint made from WPUA emulsion on aluminum foil paper was investigated. The results show that the WPUA emulsion modified with vinyl monomer has good stability,and the emulsion can coexist with ethanol without demulsification. The particle sizes of the modified WPUA emulsion increase and the particle size distribution is uniform. The heat resistance of the modified WPUA films is enhanced,the glass transition temperature is increased,and the crystallinity is weakened. The flexibility,gloss,adhesion of WPUA on aluminum foil paper are not affected,while the heat resistance is improved by modification with vinyl monomers. WPUA meets the requirements of the printing industry. Organic solvents are not required during the preparation and application process of WPUA. It meets the national standards for cigarettes packaging products and it is suitable for the promotion and application as gloss oil for packaging and printing.关键词
水性聚氨酯/复合乳液/胶膜/乙烯基单体/改性/烟包印刷Key words
waterborne polyurethane/composite emulsion/film/vinyl monomer/modification/cigarette package printing分类
化学化工引用本文复制引用
赖小娟,刘贵茹,赵倩云,易永根,王磊..乙烯基单体改性水性聚氨酯的合成及其用于烟包印刷用光油[J].石油化工,2018,47(5):486-492,7.基金项目
陕西省工业科技攻关项目(2016GY-241,2016GY-193) （2016GY-241,2016GY-193）
陕西省科技成果转移与推广计划项目(2017CGZH-XNGJ-07) （2017CGZH-XNGJ-07）
西安市科技计划项目(2017068CG/RC031(SXKD005)). （2017068CG/RC031(SXKD005）
