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氨基改性纳米纤维素气凝胶的制备及吸附性能研究

张天蒙 张洋 刘双 江华 姚远

西南林业大学学报2018,Vol.38Issue(3):181-187,7.
西南林业大学学报2018,Vol.38Issue(3):181-187,7.DOI:10.11929/j.issn.2095-1914.2018.03.026

氨基改性纳米纤维素气凝胶的制备及吸附性能研究

Preparation and Adsorption Properties of Ammonia Modified Nano Cellulose Aerogels

张天蒙 1张洋 1刘双 1江华 2姚远1

作者信息

  • 1. 南京林业大学材料科学与工程学院,江苏 南京210037
  • 2. 南京林业大学化学工程学院,江苏 南京210037
  • 折叠

摘要

Abstract

In order to improve and enhance the adsorption selectivity and adsorption capacity of nano cellulose (CNF) aerogels on CO2,The spherical hydrogels prepared were graft modified with 3-(2-aminoethylamino) propyl-methyldimethoxysilane as modifier, and then freeze-dried to prepare amino-modified CNF aerogels. The aerogels were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, specific surface area porosimeter,and conduct CO2adsorption/desorption test. The results showed that the adsorption capacity of modi-fied CNF aerogels increased with the increase of nitrogen content. When the initial pressure is 0.13 MPa and the temperature is 20℃,the maximum CO2adsorption capacity is 1.80 mmol/g,which is much larger than that of un-modified CNF aerogels. After 10 adsorption/desorption cycles,its adsorption capacity is basically stable with good regeneration capacity.

关键词

纳米纤维素/气凝胶/氨基改性/吸附/CO2

Key words

nano cellulose/aerogels/amino modification/adsorption/CO2

分类

农业科技

引用本文复制引用

张天蒙,张洋,刘双,江华,姚远..氨基改性纳米纤维素气凝胶的制备及吸附性能研究[J].西南林业大学学报,2018,38(3):181-187,7.

基金项目

林业公益性行业科研专项项目(201504603)资助. (201504603)

西南林业大学学报

OA北大核心CSTPCD

2095-1914

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