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水蒸气活化法制备长柄扁桃壳基介孔活性炭的研究

李少妮 孙康 申烨华 李聪 李继辉

生物质化学工程2018,Vol.52Issue(3):9-15,7.
生物质化学工程2018,Vol.52Issue(3):9-15,7.DOI:10.3969/j.issn.1673-5854.2018.03.002

水蒸气活化法制备长柄扁桃壳基介孔活性炭的研究

Preparation of Mesoporous-activated Carbon from Amygdalus Pedunculata Shell by Steam Activation

李少妮 1孙康 2申烨华 1李聪 2李继辉2

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所 生物质化学利用国家工程实验室 国家林业局 林产化学工程重点开放性实验室 江苏省 生物质能源与材料重点实验室,江苏 南京 210042
  • 2. 合成与天然功能分子化学教育部重点实验室 西北大学 化学与材料科学学院 国家林业局 长柄扁桃工程技术研究中心 榆林市沙漠植物资源重点实验室 陕西省醇醚及生物质能源工程研究中心,陕西 西安 710069
  • 折叠

摘要

Abstract

Activated carbon with developed mesopore were prepared from Amygdalus pedunculata shell by steam activation at different technology condition.The effects of carbonization temperature, activation temperature, activation time and steam dosage on the adsorption properties and yield of resulting activated carbon were analyzed.The results showed that the optimal activated carbon was obtained at carbonization temperature 600℃, activation temperature 850℃, activation time 60 min and steam/carbide weight ratio 6:1, whose yield, iodine value, methylene blue value, mesopore ratio, BET surface area and average pore size were 12%, 1175 mg/g, 315 mg/g, 60.9%, 1127 m2/g and 2.6 nm, respectively.Besides, the results of adsorption experiment indicated that the activated carbon prepared at the optimal conditions was promising absorbent for cephalexin, the equilibrium adsorption capacity could reach 245 mg/g after 24 h, which was higher than that of coconut shell activated carbon and walnut shell activated carbon prepared under the same conditions.

关键词

长柄扁桃壳/水蒸气活化/介孔活性炭/头孢氨苄

Key words

Amygdalus pedunculata shell/steam activation/mesoporous-activated carbon/cephalexin

分类

化学化工

引用本文复制引用

李少妮,孙康,申烨华,李聪,李继辉..水蒸气活化法制备长柄扁桃壳基介孔活性炭的研究[J].生物质化学工程,2018,52(3):9-15,7.

基金项目

国家自然科学基金面上项目(31770629) (31770629)

生物质化学工程

OA北大核心

1673-5854

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