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La-TiO2/SiO2光降解催化剂的制备及性能

樊国栋 郑少芳 樊苗苗 李连红

陕西科技大学学报2018,Vol.36Issue(3):107-112,6.
陕西科技大学学报2018,Vol.36Issue(3):107-112,6.

La-TiO2/SiO2光降解催化剂的制备及性能

Preparation and properties of La-TiO2/SiO2 photodegradation catalyst

樊国栋 1郑少芳 1樊苗苗 1李连红1

作者信息

  • 1. 陕西科技大学化学与化工学院教育部轻化工助剂化学与技术重点实验室 ,陕西西安 710021
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摘要

Abstract

The photocatalysts of (xwt% )La-TiO2/SiO2 (x=0 .5~3 .0) were prepared with (Si(OC2H5 )4 ) ,(Ti(OC2H5 )4 and(La2O3 )as precursors via a sol-gel method .The samples were characterized by X-ray diffraction (XRD) ,scanning electron microscopy (SEM ) ,specific surface area analyzer (BET ) ,Fourier transform infrared spectroscopy (FT-IR ) and X-ray photoelectron spectroscopy (XPS) ,respectively .Using rhodamine B (RhB) as model pollu-tant ,the effects of the addition of La on photocatalytic efficiency of TiO2/SiO2 (the molar ra-tio of SiO2 to TiO2 was 1:7) catalyst were investigated under visible light and UV light conditions ,respectively .The results showed that the doping amount of La was 2% ,the pho-tocatalytic efficiency of the La-TiO2/SiO2 was the best .After 150 min visible light and 75 min UV light irradiation ,the degradation rate of Rh B reached 99 .2% and 71 .3% respective-ly .

关键词

溶胶-凝胶法/La掺杂TiO2/光催化降解/TiO2-SiO2

Key words

sol-gel method/La doped TiO2/photocatalytic degradation/TiO2-SiO2

分类

化学化工

引用本文复制引用

樊国栋,郑少芳,樊苗苗,李连红..La-TiO2/SiO2光降解催化剂的制备及性能[J].陕西科技大学学报,2018,36(3):107-112,6.

基金项目

陕西省科技厅工业科技攻关计划项目(2016GY-142) (2016GY-142)

陕西省教育厅重点实验室科研计划项目(14JS015) (14JS015)

陕西科技大学学报

OACSTPCD

2096-398X

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