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EVOH-SO3Li/PET电纺锂离子电池隔膜电化学性能

巩桂芬 王磊 兰健

材料工程2018,Vol.46Issue(3):7-12,6.
材料工程2018,Vol.46Issue(3):7-12,6.DOI:10.11868/j.issn.1001-4381.2016.000232

EVOH-SO3Li/PET电纺锂离子电池隔膜电化学性能

Electrochemical Properties of EVOH-SO3Li/PET Lithium Ion Battery Separator via Electrospinning

巩桂芬 1王磊 1兰健1

作者信息

  • 1. 哈尔滨理工大学材料科学与工程学院,哈尔滨150040
  • 折叠

摘要

Abstract

EVOH-SO3 Li/PET Li-ion battery composite membranes were prepared by means of alternated electrostatic spinning,then the morphology of the membranes was observed by scanning electron microscope,and the electrochemical properties of the membranes were tested by using an electrochemistry work station.The results show that the average diameter of EVOH-SO3Li/PET fibre is 387nm,both two kinds of fibres exhibit uniform net-like structure.Compared with pure EVOHSO3Li fibre,adhesion phenomenon of modified EVOH-SO3 Li/PET fibre is not obvious anymore,and the surface of EVOH-SO3Li/PET fibre becomes more smooth with enlarged pores between adjacent fibres;the electrochemical window of EVOH-SO3Li/PET separator is 5.3V,bulk resistance of EVOH-SO3Li/PET is decreased to 212.31Ω,and the ion conductivity of EVOH-SO3Li/PET separator is 2.347 × 10-3 S/cm,the properties of EVOH-SO3Li/PET membranes are improved compared with EVOH-SO3Li.

关键词

锂离子电池隔膜/聚对苯二甲酸乙二醇酯/EVOH-SO3Li/静电纺丝/电化学性能

Key words

lithium-ion battery separator/PET/EVOH-SO3Li/electrostatic spinning/electrochemical property

分类

化学化工

引用本文复制引用

巩桂芬,王磊,兰健..EVOH-SO3Li/PET电纺锂离子电池隔膜电化学性能[J].材料工程,2018,46(3):7-12,6.

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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