福州大学学报（自然科学版）2018，Vol.46Issue(3)：422-430,9.DOI:10.7631/issn.1000-2243.17239
含氟茂铁吡唑类衍生物的合成及燃速催化性能的研究
Synthesis and burning-rate catalysis performance of fluorine-containing ferrocenyl pyrazolines
摘要
Abstract
Three ferrocenyl chalcones(1a-1c) were synthesized by the aldol condensation reaction of acetylferrocene with substituted benzaldehyde. Then hydrazine hydrate was condensated with them to construct three kinds of pyrazolines(2a-2c). Finally, 2a-2c were acylated with corresponding benzoyl chlorides to obtain five novel 3-ferrocenyl-5-phenyl-1-benzoylpyrazolines(3a-3e). These com-pounds were structurally characterized by IR, MS, 1 H NMR, 19 F NMR, 13 C NMR, HRMS. Electro-chemical properties of these compounds were studied by CV and DPV. Thermal behavior and catalytic performance for thermal decomposition of AP were studied by TG and DSC. The results indicated that synthetic molecules all have efficient catalytic effect on the thermal decomposition of AP . What ' s more, when electron withdrawing group of fluorine was brought in, the polarity increased and the burn-ing-rate catalysis performance slightly weakened.关键词
二茂铁/吡唑啉/含氟基团/高氯酸铵/燃速催化Key words
ferrocenyl/pyrazoline/fluorine-containing groups/ammonium perchlorate/burning-rate catalysis分类
化学化工引用本文复制引用
袁耀锋,杨思涵,王吉成,林芬..含氟茂铁吡唑类衍生物的合成及燃速催化性能的研究[J].福州大学学报（自然科学版）,2018,46(3):422-430,9.基金项目
福建省科技厅产学研重点资助项目(G2015H6010) （G2015H6010）
福州大学2016年大学生创新创业训练计划资助项目(201610386008) （201610386008）
