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核壳结构分子筛β@IISERP-COF2小球的合成

黄薇薇 任家旺 方千荣 Valentin VALTCHEV

高等学校化学学报2018,Vol.39Issue(6):1127-1131,5.
高等学校化学学报2018,Vol.39Issue(6):1127-1131,5.DOI:10.7503/cjcu20180071

核壳结构分子筛β@IISERP-COF2小球的合成

Synthesis of Zeolite β@IISERP-COF2 Core-shell Hybrid Materials

黄薇薇 1任家旺 1方千荣 1Valentin VALTCHEV1

作者信息

  • 1. 吉林大学化学学院,长春130012
  • 折叠

摘要

Abstract

Zeolite β was crystallized from precursor solutions within the pores of anion exchange resin beads. Resin beads as sacrificial template was removed by calcination leaving stable beads of zeolite β. We use the zeolite β beads as substrate to cover a layer hydrophobic IISERP-COF2, termed as zeolite β@IISERP-COF2. There is definite advantage in transferring the hydrophobicity of COFs to zeolite to aid their adsorb CO2 in humid environment. Water adsorption capacity( measured under 79% humidity) of zeolite β@IISERP-COF2 ( 2. 1%) shows a significant decrease compared to that of zeolite β( 11. 0%) .

关键词

分子筛β小球/共价有机骨架材料/核壳结构/疏水性

Key words

Zeolite β beads/Covalent organic frameworks( COFs)/Core-shell/Hydrophobicity

分类

化学化工

引用本文复制引用

黄薇薇,任家旺,方千荣,Valentin VALTCHEV..核壳结构分子筛β@IISERP-COF2小球的合成[J].高等学校化学学报,2018,39(6):1127-1131,5.

基金项目

国家自然科学基金(批准号:21571078, 21571079)资助. Supported by the National Natural Science Foundation of China( Nos.21571078, 21571079) . (批准号:21571078, 21571079)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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