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超滤在乙醇厌氧沼液资源化回用中的应用

王团 薛宏光 王柯 毛忠贵 张建华

环境工程学报2018,Vol.12Issue(4):1046-1054,9.
环境工程学报2018,Vol.12Issue(4):1046-1054,9.DOI:10.12030/j.cjee.201710039

超滤在乙醇厌氧沼液资源化回用中的应用

Application of ultrafiltration in treatment of ethanol anaerobic digestion effluent for recycling use

王团 1薛宏光 2王柯 3毛忠贵 1张建华2

作者信息

  • 1. 江南大学生物工程学院,无锡214122
  • 2. 江南大学工业生物技术教育部重点实验室,无锡214122
  • 3. 江苏金茂源生物化工有限责任公司,连云港222111
  • 折叠

摘要

Abstract

Recycling the treated anaerobic digestion effluent (ADE) for use in ethanol production process can alleviate some problems such as large water consumption in production process and the subsequent expensive wastewater treatment for standardized discharge.Considering that ultrafiltration (UF) membrane is instrumental for the removal of microorganisms contained in the ADE,this method focused on the feasibility of tubular ultrafiltration (UF) membrane to treat the ADE for the future recycling use.Results showed that the reasonable condition was the ADE temperature of 50 ℃,membrane surface velocity of 4.5 m·s-1 and water production rate of 30%.Under the controlled condition,a desired membrane flux was obtained to be 174 L·(m2·h)-1.Further,the membrane fouling was taken into consideration.It was found that the pollutants should be divided into inorganic compounds,mainly consisting of metal elements Ca2+,Mg2+,Fe3+,and organic substances,i.e.,hydrocarbons,fatty acids and their derivatives,humic acid and fulvic acid.Exploration of membrane washing method showed that these foulants were removed using citric acid and sodium hypochlorite solution,followed by sodium hydroxide solution.With this membrane washing method,the membrane flux recovered above 98%.These results indicate that the UF treatment can effectively remove the microorganisms living in the ADE to avoid the slurry acidification in the ethanol production process.

关键词

超滤/去除微生物/厌氧沼液/回用/膜污染和清洗

Key words

ultrafiltration/removal of microorganism/anaerobic digestion effluent/recycling use/membrane fouling and washing

分类

资源环境

引用本文复制引用

王团,薛宏光,王柯,毛忠贵,张建华..超滤在乙醇厌氧沼液资源化回用中的应用[J].环境工程学报,2018,12(4):1046-1054,9.

基金项目

国家自然科学基金青年科学基金资助项目(21506075) (21506075)

江苏省自然科学基金青年基金资助项目(BK20150131) (BK20150131)

111引智计划(111-2-06):江苏省连云港市“港城英才计划” (111-2-06)

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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