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全取代环戊基五元瓜环与铈(Ⅲ)配合物的合成、晶体结构及应用探索

刘玲菲 魏连通 周开志 罗娜 马培华

人工晶体学报2018,Vol.47Issue(3):510-513,521,5.
人工晶体学报2018,Vol.47Issue(3):510-513,521,5.

全取代环戊基五元瓜环与铈(Ⅲ)配合物的合成、晶体结构及应用探索

Synthesis, the Crystal Structure and Application of Fully Substituted Cyclopentano Cucurbit [5] uril with Ce (Ⅲ)

刘玲菲 1魏连通 2周开志 1罗娜 1马培华1

作者信息

  • 1. 贵州大学化学与化工学院化学系,贵阳550025
  • 2. 贵阳北控水务有限责任公司水质监测中心,贵阳550001
  • 折叠

摘要

Abstract

Coordination of fully substituted cyclopentano cucurbit [5] uril (CyP5Q [5] with Ce3 + in the presence of tetrachloridezicate anions was investigated.Single-crystal X-ray diffraction analysis revealed that the CyP5Q [5]-Ce3+ interaction systems an molecular capsule,and that a chloride anion was included in the cavity of the CyP5Q [5] molecule.and [ZnCl4] 2-anions in particular played the role of linkers,resulting in the formation of a linear supramolecular.The adsorption of seven volatile organic compounds by this complex was studied.

关键词

全取代环戊基五元瓜环/晶体结构/分子胶囊/吸附材料

Key words

fully substituted cyclopentano cucurbit [5] uril/crystal structure/molecular capsule/absorption materials

分类

化学化工

引用本文复制引用

刘玲菲,魏连通,周开志,罗娜,马培华..全取代环戊基五元瓜环与铈(Ⅲ)配合物的合成、晶体结构及应用探索[J].人工晶体学报,2018,47(3):510-513,521,5.

基金项目

贵州大学国家级大学生创新性试验计划项目(201610657026) (201610657026)

人工晶体学报

OA北大核心CSTPCD

1000-985X

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