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壳聚糖季铵盐的制备及其对铀的吸附性能研究

王凤菊 勾阳飞 宿延涛 陈树森

湿法冶金2018,Vol.37Issue(3):216-220,5.
湿法冶金2018,Vol.37Issue(3):216-220,5.DOI:10.13355/j.cnki.sfyj.2018.03.010

壳聚糖季铵盐的制备及其对铀的吸附性能研究

Synthesis and Adsorption Performance for Uranium of Chitosan Quaternary Ammonium Salt

王凤菊 1勾阳飞 1宿延涛 1陈树森1

作者信息

  • 1. 核工业北京化工冶金研究院 ,北京 101149
  • 折叠

摘要

Abstract

The spherical chitosan quaternary ammonium salt which is a kind of chitosan matrix strong alkaline adsorbent was prepared by the reactions of chitosan with glutaraldehyde ,epichlorohydrin , trimethylamine aqueous solution in turn .The adsorbent was characterized by infrared ,thermal analysis , and its adsorption performance for uranium were examined .The prepared chitosan quaternary ammonium has good adsorption effect for uranium in the solution containing low concentration of uranium .For the uranyl wastwater from a certain uranium mine whose initial concentration of uranium is 2 mg/L ,the uranium concentration can be dropped below 0 .05 mg/L by shaking adsorption with the adsorbent and meets the wastewater discharge standard .

关键词

壳聚糖/三甲胺/季铵盐/吸附剂/

Key words

chitosan/trimethylamine/quaternary ammonium salt/adsorbent/uranium

分类

化学化工

引用本文复制引用

王凤菊,勾阳飞,宿延涛,陈树森..壳聚糖季铵盐的制备及其对铀的吸附性能研究[J].湿法冶金,2018,37(3):216-220,5.

基金项目

国家自然科学基金青年科学基金资助项目(51104061 ). (51104061 )

湿法冶金

OA北大核心

1009-2617

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