林产化学与工业2018，Vol.38Issue(3)：1-16,16.DOI:10.3969/j.issn.0253-2417.2018.03.001
半纤维素选择性催化制备糠醛及其衍生物的研究进展
Research Advances in Preparation of Furfural and Its Derivatives by Selective Catalytic Conversion of Hemicellulose
摘要
Abstract
The utilization of renewable biomass resources play an important role in solving the energy crisis and reducing environmental pollution. Along this background, the production of furan-based chemicals from lignocellulose becomes one of the research focuses in biorefinery. Furfural is the key furan-based building block, which is manufactured from hemicellulose fraction directly, and offers a promising, rich platform for lignocellulosic biofuels and value-added chemicals. So it is of great practical significance to develop green technologies for the production of furfural and the conversion of furfural to primary furan-based chemicals. In this review, the formation routes and catalytic conversion of hemicellulose into furfural were summarized with special attentions on the heterogeneous acid-catalysts for the production of furfural in the liquid phase, including zeolites, metal oxides, ion-exchange resins, clays and carbon materials. The formation routes and technologies starting from furfural to various furan-based chemicals, including furfuryl alcohol, tetrahydrofurfuryl alcohol, 2-methylfuran, 2-methyltetrahydrofuran, furan, tetrahydrofuran, were reviewed.关键词
半纤维素/选择性催化/糠醛/呋喃化学品Key words
Key word:hemicellulose/selective catalysis/furfural/furan-based chemicals分类
化学化工引用本文复制引用
卢怡,郑志锋,黄元波,李文斌..半纤维素选择性催化制备糠醛及其衍生物的研究进展[J].林产化学与工业,2018,38(3):1-16,16.基金项目
国家自然科学基金资助项目(31670599) （31670599）
云南省新能源重大专项资助项目(新能源[2015]86号) （新能源[2015]86号）
云南省教育厅科学研究基金重大专项资助项目(ZD2014012) （ZD2014012）
