苏州科技大学学报（自然科学版）2018，Vol.35Issue(2)：41-44,4.DOI:10.12084/j.issn.2096-3289.2018.02.009
羟甲基膦杂环状甲基膦酸酯的合成与应用
Synthesis and application of hydroxymethyl phosphine heterocyclic methylphosphonate
摘要
Abstract
An organic phosphine flame retardant,1-methyl-4-hydroxymethyl-2,6-dioxa-1,4-diphosphinane, was synthesized by tris (hydroxymethyl) phosphine and dimethyl methylphosphonate. The effects of molar ratio , reaction temperature and reaction time on the yield were investigated. The optimal conditions were as follows:n(THMP):n(DMMP) is 1.04:1. The reaction kept going at 150 ℃ for 4 h,the yield can reach 91.6%. The structure and flame retardance of the product were characterized by means of FTIR, 1H-NMR, and LOI. The application in unsaturated resin and epoxy resin shows that the product has a good flame retardant effect.关键词
有机膦阻燃剂/三羟甲基膦/甲基膦酸二甲酯/成炭剂Key words
organic phosphine flame retardant/tris (hydroxymethyl) phosphine/dimethyl methylphosphonate/charring agentt分类
化学化工引用本文复制引用
王世杰,陆赞,杨珂珂,王彦林..羟甲基膦杂环状甲基膦酸酯的合成与应用[J].苏州科技大学学报（自然科学版）,2018,35(2):41-44,4.基金项目
苏州市应用基础工业项目(SYG201243) （SYG201243）
