天津科技大学学报2018，Vol.33Issue(2)：1-12,19,13.DOI:10.13364/j.issn.1672-6510.20170185
儿茶酚硼烷及其衍生物在有机反应中的应用进展
Progress of the Application of Catecholborane and its Derivatives in Organic Reaction
摘要
Abstract
Catecholborane(HBcat)can be prepared with several methods.It is stable,easy for storage,and can react with olefins and alkynes quickly under mild conditions.During the hydroboration process,it not only shows the characteristics of high selectivity and stereoselectivity,but also functionalizes and radicalizes easily,so it has been widely used in hydroboration and reduction reactions.In this paper,the synthesis methods and properties of catecholborane were briefly summarized,and the application of catecholborane and its derivatives in hydroboration,reduction,deoxygenation and free radical reaction are detailedly introduced.The prospect of catecholborane and its derivatives in organic reaction are also discussed.关键词
儿茶酚硼烷/硼氢化反应/还原反应/自由基反应Key words
catecholborane/hydroboration/reduction reaction/radical reaction分类
化学化工引用本文复制引用
姜涛,王合营,许芳,崔崑,马志..儿茶酚硼烷及其衍生物在有机反应中的应用进展[J].天津科技大学学报,2018,33(2):1-12,19,13.基金项目
国家自然科学基金资助项目(21374130) （21374130）
