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表面活性剂修饰碳酸氧铋的制备及光催化性能

李桂水 胡旭敏 程丽君 郝亮

应用化学2018,Vol.35Issue(6):692-699,8.
应用化学2018,Vol.35Issue(6):692-699,8.DOI:10.11944/j.issn.1000-0518.2018.06.170235

表面活性剂修饰碳酸氧铋的制备及光催化性能

Preparation and Photocatalytic Properties of Bismuth Subcarbonate Modified with Surfactants

李桂水 1胡旭敏 1程丽君 1郝亮1

作者信息

  • 1. 天津科技大学机械工程学院,天津市轻工与食品工程机械装备集成设计与在线监控重点实验室 天津300222
  • 折叠

摘要

Abstract

Bi2O2CO3 was synthesized by surfactant-assisted hydrothermal method.The dosage of cationic surfactant cetyltrimethylammonium bromide ( CTAB ) , nonionic surfactant polyethylene glycol 8000 (PEG8000), anionic surfactant sodium dodecyl sulfate(SDS), and coupling of SDS with CTAB as well as their influences on crystal plane, morphology, photoabsorption ability and photocatalytic activity of Bi2O2CO3 photocatalyst were investigated.The photocatalytic activity was evaluated by the degradation of rhodamine B solution(10 mg/L) under ultraviolet light irradiation.The results show that when the addition of Bi2O2 CO3 is 6 mmol(2.9106 g) , modified Bi2O2CO3 with SDS will inhibits the photocatalytic activity.The photocatalytic activity of Bi2O2CO3 is effectively improved by addition of 0.6 g CTAB in the hydrothermal process .A totally 0.3 g of SDS and CTAB can improve the photocatalytic activity of Bi2O2CO3 .Addition of 0.3 g PEG8000 also promotes the photocatalytic activity of Bi2O2CO3 .

关键词

光催化/碳酸氧铋/表面活性剂/罗丹明B

Key words

photocatalysis/bismuth carbonate/surfactant/rhodamine B

分类

化学化工

引用本文复制引用

李桂水,胡旭敏,程丽君,郝亮..表面活性剂修饰碳酸氧铋的制备及光催化性能[J].应用化学,2018,35(6):692-699,8.

基金项目

天津科技大学青年创新基金(2015LG11)资助 Supported by the Youth Innovation Foundation of Tianjin University of Science & Technology(No.2015LG11) (2015LG11)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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