青岛大学学报（自然科学版）2018，Vol.31Issue(1)：29-34,6.DOI:10.3969/j.issn.1006-1037.2018.02.07
对阴极材料Li1.2Fe0.052Ni0.078Co0.13Mn0.54O2/C的电化学性能的研究
Electrochemical Performance of Li1.2Fe0.052Ni0.078Co0.13Mn0.54O2/C as Cathode Materials
摘要
Abstract
The Li1.2Fe0.052Ni0.078Co0.13Mn0.54O2 cathode material with MnO2 as template shows excellent electrochemical performance by carbon surface treatment and moderate iron ion replacement of nickel ions.XRD analysis shows that the obtained materials have a layered α-NaFeO2 structure.Meanwhile,the transmission electron microscopy confirms that a clear boundary can be seen due to the carbon surface treatment.The sample delivers a discharge capacity of 210(mA · h/g) at 0.1 C rate and the capacity retention rate is about 86 ％ after 50 cycles between 2.5 and 4.8 V.关键词
锂离子电池/阴极材料/碳表面处理/空心球壳结构Key words
lithium-ion batteries/cathodes material/hollow microspheres/carbon surface modified分类
数理科学引用本文复制引用
徐宪堂,王瑞琦,王贺,常明宁,袁峰,徐胜..对阴极材料Li1.2Fe0.052Ni0.078Co0.13Mn0.54O2/C的电化学性能的研究[J].青岛大学学报（自然科学版）,2018,31(1):29-34,6.基金项目
国家自然科学基金(批准号:11547034,11647168)资助. （批准号:11547034,11647168）
