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Mg-Al-Pb及Mg-Al-Pb-Zn合金在3.5%/NaCl溶液中的腐蚀行为

殷立勇 周威 王平安

材料科学与工程学报2018,Vol.36Issue(3):408-417,469,11.
材料科学与工程学报2018,Vol.36Issue(3):408-417,469,11.DOI:10.14136/j.cnki.issn1673-2812.2018.03.012

Mg-Al-Pb及Mg-Al-Pb-Zn合金在3.5%/NaCl溶液中的腐蚀行为

Corrosion Behavior of Mg-Al-Pb and Mg-Al-Pb-Zn Alloys in 3.5% NaCl Solution

殷立勇 1周威 1王平安1

作者信息

  • 1. 中国电子科技集团第十八研究所,天津 300381
  • 折叠

摘要

Abstract

The corrosion behavior of Mg-Al-Pb and Mg-Al-Pb-Zn alloys in 3.5% NaCl solution was investigated by electrochemical measurement ,immersion test and corrosion morphology observation . The results indicate that there is an incubation period at the corrosion onset during which the corrosion rate is low . Thereafter ,the corrosion comes into steady state ,especially after long time immersion .For the solution treated (T4) specimens ,the corrosion takes place along the grain boundaries and is first inhibited by zinc in incubation period of time and then accelerated also by the zinc after the incubation and long time immersion .For the as-cast specimens ,the corrosion was initiated around the second phases ,which hinder the corrosion when immersed for a long time .The hydrogen evolution rate of both Mg-Al-Pb and Mg-Al-Pb-Zn alloys increases linearly with the increasing surface roughness of the corroding alloys after long time immersion when steady state has been established .

关键词

海水电池/镁阳极/电化学/腐蚀

Key words

seawater battery/magnesium anode/electrochemical/corrosion

分类

矿业与冶金

引用本文复制引用

殷立勇,周威,王平安..Mg-Al-Pb及Mg-Al-Pb-Zn合金在3.5%/NaCl溶液中的腐蚀行为[J].材料科学与工程学报,2018,36(3):408-417,469,11.

基金项目

Funded by Natural Science Foundation of Hunan province (2016JJ2147) and Science and Technology Plan Projects of Hunan Province (2015JC3004) (2016JJ2147)

材料科学与工程学报

OA北大核心CSCDCSTPCD

1673-2812

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