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一种聚合物型曼尼希碱的研制

张守庆 黄玮 李飞 丛玉凤 张晓琳

辽宁石油化工大学学报2018,Vol.38Issue(3):19-22,4.
辽宁石油化工大学学报2018,Vol.38Issue(3):19-22,4.DOI:10.3969/j.issn.1672-6952.2018.03.004

一种聚合物型曼尼希碱的研制

Development of a Type of Polymeric Mannich Bases

张守庆 1黄玮 1李飞 1丛玉凤 1张晓琳2

作者信息

  • 1. 辽宁石油化工大学 化学化工与环境学部,辽宁 抚顺 113001
  • 2. 中国石油抚顺石化公司 石油一厂,辽宁 抚顺 113006
  • 折叠

摘要

Abstract

A new type Mannich base was developed by the reaction of binary copolymer AM/C9 synthesized from C9 petroleum fractions with acrylamide as raw materials.The effects of reaction time,reaction temperature,pH of solution and ratio of aldehyde were studied.The apparent viscosity of Mannich was characterized by IR spectroscopy and its structure is characterized.Finally,the performance of the product is analyzed.The results show that the optimum reaction conditions were as follows:The reaction time is 4 h,the reaction temperature is 70 ℃,the pH is 9 and the ratio of dimethylamine to formaldehyde was 1.5.The result of infrared spectrum characterization shows that the product has been synthesized.Synthetic Mannich base has higher viscosity,temperature and salt tolerance compared with traditional HPAM.

关键词

曼尼希反应/表观黏度/耐温耐盐

Key words

Mannich reaction/Apparent viscosity/Temperature and salt resistant

分类

能源科技

引用本文复制引用

张守庆,黄玮,李飞,丛玉凤,张晓琳..一种聚合物型曼尼希碱的研制[J].辽宁石油化工大学学报,2018,38(3):19-22,4.

基金项目

辽宁省大学生创新创业训练计划项目(201610148007) (201610148007)

辽宁石油化工大学教学改革项目(20165230070018). (20165230070018)

辽宁石油化工大学学报

1672-6952

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