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片段组装技术研发铜钼分离高效抑制剂

吴桂叶 刘慧南 刘崇峻 宋振国 朱阳戈 刘龙利

矿产保护与利用Issue(3):22-25,30,5.
矿产保护与利用Issue(3):22-25,30,5.DOI:10.13779/j.cnki.issn1001-0076.2018.03.004

片段组装技术研发铜钼分离高效抑制剂

Using Fragment-assembly to Research High Efficiency Copper-molybdenum Separation Inhibitor

吴桂叶 1刘慧南 2刘崇峻 1宋振国 2朱阳戈 1刘龙利2

作者信息

  • 1. 北京矿冶科技集团有限公司,北京102628
  • 2. 矿物加工科学与技术国家重点实验室,北京102628
  • 折叠

摘要

Abstract

Reagents are the core to achieve the separation of copper and molybdenum.NaHS (Na2S), Knox reagent, sodium thioglycolate and cyanide are commonly used copper molybdenum inhibitors, with the problems of the high dosage, high cost, severe environmental pollution, low in-dustrial applicability and etc.To solve these problems, based on fragment assembly used in study, the method " screening to identify lead compounds, splicing and reassembling the lead compound, with the combination of computer aided molecular design techniques" was conducted to efficient in-hibitor BK511.Material Studios ( MS) software was used to calculate the interaction between BK511 and chalcopyrite.The results illustrated that the interaction between BK511 and chalcopy-rite is significantly greater than that of NaHS and etc, to achieve selective inhibition of chalcopy-rite.The industrial application of Cu-Mo separation showed that BK511 displayed outstanding in-hibition performance with only 10%~20%dosage of NaHS, which is a solid candidate to substi-tute NaHS with much lower reagent cost and better environment footprint.The sulfide content is dramatically reduced in the tailings of the processing plant in the industry.

关键词

片段组装技术/铜钼分离/抑制剂

Key words

fragment assembly/copper-molybdenum separation/inhibitor

分类

矿业与冶金

引用本文复制引用

吴桂叶,刘慧南,刘崇峻,宋振国,朱阳戈,刘龙利..片段组装技术研发铜钼分离高效抑制剂[J].矿产保护与利用,2018,(3):22-25,30,5.

基金项目

北京矿冶研究总院科研项目(2016-03) (2016-03)

矿产保护与利用

OACSTPCD

1001-0076

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