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稀土矿浮选中Ce3+离子对方解石的活化作用机理研究

屈奇奇 曹钊 张文博 胡轶文 黄英豪 许杰

矿产保护与利用Issue(3):71-76,6.
矿产保护与利用Issue(3):71-76,6.DOI:10.13779/j.cnki.issn1001-0076.2018.03.013

稀土矿浮选中Ce3+离子对方解石的活化作用机理研究

Research on Activation Mechanism of Ce3+ Ions on Calcite in Rare Earth Ore Flotation

屈奇奇 1曹钊 1张文博 1胡轶文 1黄英豪 1许杰1

作者信息

  • 1. 内蒙古科技大学矿业研究院,内蒙古包头014010
  • 折叠

摘要

Abstract

The activation mechanism of Ce3+ ions on calcite in rare earth ore flotation using octano-hydroxamic acid as collector was studied by single mineral flotation experiment, IR spectroscopy and Zeta potential measurement.The flotation results show that Ce3+ ions could activate the flota-tion of calcite at pH 6~11 when the Ce3+ concentration was less than 1×10 -4mol/L and OHA concentration was 2.5×10 -4mol/L.The mechanism results show that Ce3+ ions could act as the active site on calcite surface, which reacted with OHA ions to form stable five-membered ring chelate.Therefore, the adsorption of collector OHA on calcite was promoted and thus calcite flota-tion was activated.

关键词

方解石/氟碳铈矿/Ce3+离子/活化

Key words

calcite/bastnaesite/Ce3+ ions/activation

分类

矿业与冶金

引用本文复制引用

屈奇奇,曹钊,张文博,胡轶文,黄英豪,许杰..稀土矿浮选中Ce3+离子对方解石的活化作用机理研究[J].矿产保护与利用,2018,(3):71-76,6.

基金项目

国家自然科学基金(51764045) (51764045)

内蒙古自治区研究生科研创新项目(S20171012703) (S20171012703)

矿产保护与利用

OACSTPCD

1001-0076

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