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EDTA二钠钙对十二胺体系中菱锌矿浮游性的影响

张威 毕洪山 张津 李国栋 郝海永 韩聪 魏德洲 沈岩柏

矿产保护与利用Issue(3):124-129,6.
矿产保护与利用Issue(3):124-129,6.DOI:10.13779/j.cnki.issn1001-0076.2018.03.022

EDTA二钠钙对十二胺体系中菱锌矿浮游性的影响

Effect of EDTA Na2-Ca on the Pelagic Activity of Smithsonite in Dodecylamine System

张威 1毕洪山 1张津 1李国栋 1郝海永 1韩聪 1魏德洲 1沈岩柏1

作者信息

  • 1. 东北大学资源与土木工程学院,辽宁沈阳110819
  • 折叠

摘要

Abstract

The influence of ethylenediamine tetraacetic acid disodium calcium ( EDTA Na2-Ca) on the flotability of smithsonite in the dodecylamine (DDA) cation flotation system was investigated by single-mineral flotation test.The results showed that EDTA Na2-Ca could not collect smith-sonite activated by sodium sulfide, but could enhance the collecting ability of DDA at pH 9.2~11.1.The better flotation performance could be achieved when the mixed collector with 40%mass ratio of DDA replaced by EDTA Na2-Ca was used.The results of flotation solution chemical cal-culation, mineral dissolution tests, and dynamic potential tests showed that EDTA Na2-Ca signifi-cantly improved the flotation recovery of smithsonite by promoting the dissolution of Zn2+ on the smithsonite surface and reducing the potential of the mineral surface.

关键词

菱锌矿/十二胺/乙二胺四乙酸二钠钙/浮选

Key words

smithsonite/dodecylamine/ethylenediamine tetraacetic acid disodium calcium/flotation

分类

矿业与冶金

引用本文复制引用

张威,毕洪山,张津,李国栋,郝海永,韩聪,魏德洲,沈岩柏..EDTA二钠钙对十二胺体系中菱锌矿浮游性的影响[J].矿产保护与利用,2018,(3):124-129,6.

基金项目

国家自然科学基金资助项目(51674067、51422402) (51674067、51422402)

中央高校基本科研业务费项目(N150101001、N160106004、N170106005) (N150101001、N160106004、N170106005)

矿产保护与利用

OACSTPCD

1001-0076

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