天然气化工2018，Vol.43Issue(3)：95-103,9.
甲醇定向转化制二甲氧基甲烷催化剂研究进展
Research progress in catalysts for direct conversion of methanol to dimethoxymethane
程金燮 1王科 1胡志彪 1林荆 1王熙庭 1谢光全 1陈鹏1
作者信息
- 1. 西南化工研究设计院有限公司,工业排放气综合利用国家重点实验室,国家碳一化学工程技术研究中心,四川 成都 610225
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摘要
Abstract
The researches on the metal catalysts and heteropolyacid catalysts applied in fixed bed process for one-step synthesis of dimethoxymethane (DMM) from methanol in recent 10 years are reviewed. Although Ru-based catalysts demonstrate low activation temperature, they are expensive and perform bad. Re-based catalysts not only exposed the problems of Ru-based catalysts, but also have high operating temperature, volatile loss and poor stability. Fe-Mo catalysts show good activity but poor selectivity, needing to match appropriate working conditions. Heteropoly acid catalysts show poor performance. They are unstable and easy to decompose, and require high reaction temperature. V-based catalysts are the most promising catalysts for industrialization due to their lower reaction temperature, better structural stability and excellent catalytic performance. It is believed that improving the activity and selectivity of V-based catalysts, studying their stability and developing appropriate reaction processes should be the key points for next stage research works. The constant breakthrough in catalyst performance and continuous improvement of technical economy will boost the industrialization of this technology.关键词
二甲氧基甲烷/直接合成/催化剂/甲醇/氧化缩合Key words
dimethoxymethane/direct synthesis/catalyst/methanol/oxidative condensation分类
化学化工引用本文复制引用
程金燮,王科,胡志彪,林荆,王熙庭,谢光全,陈鹏..甲醇定向转化制二甲氧基甲烷催化剂研究进展[J].天然气化工,2018,43(3):95-103,9.
