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碳量子点/磷酸银复合催化剂的制备及光催化性能

樊国栋 樊苗苗 郭萌 田噂存

陕西科技大学学报2018,Vol.36Issue(4):120-126,7.
陕西科技大学学报2018,Vol.36Issue(4):120-126,7.

碳量子点/磷酸银复合催化剂的制备及光催化性能

Synthesis and photocatalytic properties of carbon quantum dot/Ag3PO4 composite

樊国栋 1樊苗苗 1郭萌 1田噂存1

作者信息

  • 1. 陕西科技大学化学与化工学院教育部轻化工助剂化学与技术重点实验室,陕西西安 710021
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摘要

Abstract

Carbon quantum dot(CQDs)/Ag3PO4photocatalytic composites were synthesized by coprecipitation method using the CQDs,NaH2PO4and AgNO3as starting materials.X-ray diffraction(XRD),field-emission scanning electron microscopy(FE-SEM),X-ray photoelec-tron spectroscopy(XPS)and UV-Vis analysis were utilized to characterize the structure,morphology,chemical state of element and band gap energy as synthesized photocatalyst.The results indicated that the composites possessed a cubic phase structure and did not change Ag3PO4crystal structure.With the increasing amount of CQDs,the particle size of xCQDs/Ag3PO4decreased.The Rh B was used as the target pollutant,and the photocatalytic per-formances of xCQDs/Ag3PO4(x=0.4~2.0 wt%)were investigated under the condition of visible light irradiation.The synthesized nanocomposites of CQDs/Ag3PO4showed higher photocatalytic activity compared to conventional Ag3PO4photocatalyst,and the 1.2 w t%CQDs/Ag3PO4had the best photo-degradation performance.w hile m(CQDs): m(Ag3PO4)=1.2:100,the degradation efficiency of Rh B could reach to 91.6%after 60 min reaction under visible light irradiation.Meanwhile,good photocatalytic activity was retained after three cycles run.

关键词

碳量子点/磷酸银/复合光催化材料/罗丹明B

Key words

carbon quantum dot/Ag3PO4/photocatalytic composite/Rhodamine B

分类

化学化工

引用本文复制引用

樊国栋,樊苗苗,郭萌,田噂存..碳量子点/磷酸银复合催化剂的制备及光催化性能[J].陕西科技大学学报,2018,36(4):120-126,7.

基金项目

陕西省科技厅科技攻关计划项目(2016GY-142) (2016GY-142)

陕西省教育厅重点实验室科研计划项目(14JS015) (14JS015)

陕西科技大学学报

OACSTPCD

2096-398X

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