印染助剂2018，Vol.35Issue(6)：26-29,4.
异构十三醇聚氧乙烯(2)醚的合成
Synthesis of iso-tridecanol polyoxyethylene ether
宋明贵 1王月芬 1钱建芳 1金一丰 1余江1
作者信息
- 1. 浙江皇马科技股份有限公司,浙江绍兴 312363
- 折叠
摘要
Abstract
The iso- tridecanoI poIyoxyethyIene ether with Iow epoxide addition number was synthesized by acid cataIyst BF3·Et2O. The effects of the amount of cataIyst, reaction temperature, system pressure, reac-tion time on the residuaI of iso- tridecanoI and dioxane were investigated. The optimaI synthetic conditions of iso- tridecanoI poIyoxyethyIene ether were as foIIows: the amount of cataIyst 0.1%, reaction temperature 70 ℃, system pressure 0.2 MPa, reaction time 20 min. The iso- tridecanoI poIyoxyethyIene ether synthesized under these process was anaIyzed by gas chromatography, the residuaI amount of the raw materiaI iso- tri-decanoI was 9.8%, the amount of dioxane was 4.2×10- 6.关键词
酸性催化剂BF3·Et2O/异构十三醇聚氧乙烯醚/异构十三醇/二(噁)烷Key words
BF3·Et2O/iso- tridecanoI poIyoxyethyIene ether/iso- tridecanoI/dioxane分类
化学化工引用本文复制引用
宋明贵,王月芬,钱建芳,金一丰,余江..异构十三醇聚氧乙烯(2)醚的合成[J].印染助剂,2018,35(6):26-29,4.
