应用化学2018，Vol.35Issue(5)：511-517,7.DOI:10.11944/j.issn.1000-0518.2018.05.170162
苯甲酰咪唑过氧化反应
Peroxidation of Benzoylimidazole
摘要
Abstract
In this paper,the experimental methods for the synthesis of t-butyl peroxide compounds were discussed,in which benzoyl imidazole and t-butyl hydroperoxide(TBHP)were used as reactants,1,8-diazabicycloundec-7-ene(DBU)was used as the catalyst and acetonitrile(CH3CN)was used as the reaction solvent.The effect of catalysts and their dosage,raw material ratios,solvents and temperature on the yield were investigated.A total of 25 target products were obtained under the optimum conditions with yields of 45％～99％.The molecular structures of the products were analyzed by nuclear magnetic resonance spectroscopy(1H NMR and 13C NMR)and mass spectrometry.The method has the advantage of easily available material,easy operation,mild reaction conditions and a wide range of functional group tolerance,and has provided a new idea for the synthesis of t-butyl peroxide compounds.关键词
苯甲酰咪唑/叔丁基过氧化氢/二氮杂二环十一碳-烯催化剂/过氧化叔丁酯类化合物Key words
benzoylimidazole/t-butyl hydroperoxide/diazabicycloundec-ene catalyst/t-butyl peroxide compounds分类
化学化工引用本文复制引用
石赟,李孟生,淡艳妮..苯甲酰咪唑过氧化反应[J].应用化学,2018,35(5):511-517,7.基金项目
国家科学自然基金(21102663)、甘肃省青年科技基金计划(1107RJYA080)资助 Supported by the National Natural Science Foundation of China (No.21101663),the Gansu Province Youth Science and Technology Fund Project(No.1107RJYA080) （21102663）
