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阳离子聚合物对孤东原油乳状液的破乳研究

方洪波 林梅钦

石油化工高等学校学报2018,Vol.31Issue(4):57-62,6.
石油化工高等学校学报2018,Vol.31Issue(4):57-62,6.DOI:10.3969/j.issn.1006-396X.2018.04.011

阳离子聚合物对孤东原油乳状液的破乳研究

Demulsification of Gudong Crude Oil Emulsion by Cationic Functional Polymers and the Properties of Oil‐Water Interface

方洪波 1林梅钦2

作者信息

  • 1. 中石化石油工程设计有限公司,山东东营257026
  • 2. 中国石油大学提高采收率研究院,北京102249
  • 折叠

摘要

Abstract

A series of cationic functional polymers with different cations and molecular weights were used to determine the oil water interfacial tension ,Zeta potential and O/W emulsion stability of the oil and water of the Gudong crude oil .It was found that when the molecular weight was almost the same ,the bigger of the cationic degree ,the better ability of breaking the O/W emulsions by the polymers .And in the region of the investigated concentration ,at higher concentration of the polymer ,better demulsification effects were obtained.The results of interfacial tension and zeta potential measurements indicated that the reason of the demulsification of emulsion by this kind of cationic functional polymer was the electrical neutralization on the interface between oil and water .That is to say ,when polymer was added to the emulsion ,it could neutralize the charges on the interface and as a result the oil droplets coalescenced.

关键词

孤东原油/功能性聚合物/乳状液/界面张力/破乳

Key words

Gudong crude oil/Functional polymer/Emulsion/Interfacial tensiton/Demulsification

分类

能源科技

引用本文复制引用

方洪波,林梅钦..阳离子聚合物对孤东原油乳状液的破乳研究[J].石油化工高等学校学报,2018,31(4):57-62,6.

基金项目

国家重大科技专项资助(2011ZX05011). (2011ZX05011)

石油化工高等学校学报

OACSTPCD

1006-396X

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